Physiochemical treatment of residual water from the cromatization process

Journal: Region - Water Conservancy DOI: 10.32629/rwc.v9i1.5247

Araceli  Salazar Peralta1, J. Alfredo Pichardo Salazar2, Ulises Pichardo Salazar3, Rosa Hilda Chávez4

1. Technological Institute of Higher Studies of Jocotitlán, Mexico
2. Center for Technological, Industrial and Service High School Education, Mexico
3. Center for Technological, Industrial and Service Studies, Mexico
4. National Institute of Nuclear Research, Mexico

Abstract

The problem of environmental pollution brings with it issues that affect the development of all living beings, including plants, animals, and humans [1]. Water is one of the main natural resources affected by industrial activity, as many industrial processes depend on it for product manufacturing, or it is used as an essential auxiliary service in unit operations. Therefore, water treatment procedures must be established to help conserve its natural state and ensure its preservation for future generations [1]. Concern about environmental pollution has fostered research and development of sustainable technologies, as well as increasingly stringent regulations to ensure that industrial processes, through the use of clean technologies, reduce pollutant levels in effluents. Most companies generate wastewater with high concentrations of pollutants because treatment methods are economically unviable and have low effectiveness. In industry, chromium is used in: tanning processes, textile pigments, alloys, catalysts, anti-corrosion agents, batteries, fungicides, metal coatings, electroplating, etc. The objective of this study was to establish a methodology for reducing chromium VI to chromium III in wastewater, as well as its control to comply with the parameters established in Standard NOM-001-SEMARNAT-1996 [22]. The results obtained after treatment ranged from 0.059 to 0.99 mg/L of chromium III. It is concluded that treatment with sodium metabisulfite is a good option for chromium reduction. The key finding of this study is that the water can be reused for irrigating green areas.

Keywords

waste water; Chromium VI; sodium metabisulfite

References

[1] M. N. A. Al-Azzawi, S. M. Shartooh, S. Al-Hiyaly, "The Removal of Zinc, Chromium and Nickel from Industerial Waste-Water Using Banana Peels", Iraqi Journal of Science, pp. 72-81, 2013.
[2] Asamblea Nacional, "Decreto Ejecutivo N°. 21-2017", en La Gaceta, Diario Oficial, p. 48, 2017.
[3] B. Volesky, Z. R. Holant, "Biosorption of Heavy Metals", Biotechnol. Prog., no. 11, pp. 235-250, 1995.
[4] J. Guertin, Toxicity and Health Effects of Chromium (All Oxidation States). Chromium (VI) Handbook, pp. 215-234, 2004.
[5] OSHA, Hexavalent Chromium, Washington, 2009.
[6] EPA, Chromium Compounds, 2000, https://www.epa.gov/sites/production/files/2016-09/documents/chromium-compounds.pdf
[7] M. Aguilar, et al., "Remoción de plomo de soluciones acuosas por titanato de potasio dopado con sílice", Rev. Int. Contam. Ambient, vol.25, no. 3, pp.125-132, 2009.
[8] B. Atkinson, F. Bux, H. Kasan, Considerations for Application of Biosorption Technology to Remediate Metal-Contaminated Industrial Effluents, Water SA, pp. 129-135, 1998.
[9] S. Kamsonlian, S. Suresh, C. Majumder, S. Chand, "Characterization of Banana and Orange Peels: Biosorption Mechanism", International Journal of Science Technology & Management, pp. 1-7, 2011.
[10] Z. Abbasi, M. Alikarami, E. Nezhad, F. Moradi, V. Moradi, "Adsorptive Removal of Co2+ and Ni2+ by Peels of Banana from Aqueous Solution", Universal Journal of Chemistry, 90-95, 2003.
[11] APHA, AWWA, WEF. "Standard Methods for the Examination of Water and Wastewater", En 3500-Cr B. Colorimetric Method (pp. 69-70). Washington: American Public Health Association, 2012.
[12] A. Ashraf, S., Khalid, M. Fazal, "Removal of chromium (VI) from aqueous medium using chemically modified banana peels as efficient low-cost adsorbent", Elsevier, pp. 1-10, 2016.
[13] B. Meroufel, O. Benali, M. Benyahia, "Adsorptive removal of anionic dye from aqueous solutions by Algeriankaolin: Characteristics, isotherm, kinetic and thermodynamic studies", J. Mater. Environ. Sci., pp. 482-491, 2013.
[14] P. Deshmukh, G. Khadse, V. Shinde, P. Labhasetwar, "Cadmium Removal from Aqueous Solutions Using Dried Banana Peels as An Adsorbent: Kinetics and Equilibrium Modeling", Journal of Bioremediation & Biodegradation, no. 8, pp. 395, 2017.
[15] M. Díaz, R. Contreras, M. Guardiola, C. Mayo del Río, "Kinetic study of absorption of chromium (VI) using Canary Bananas Peels in contaminated water", International Journal of Innovation and Scientific Research, pp. 139-145, 2017.
[16] M. Kumar, C. Majumder, "Bio-absorptive Removal of Cr (VI) from Stimulated Tannery Waste Water using Different Adsorbents and Compare with GAC" Krishi Sanskriti, pp. 73-86, 2014.
[17] M. Romero-Sevilla, S. Sánchez-Cuadra, M. Benavente Silva, "Aplicación de Quitosano modificado en el tratamiento de aguas residuales de tenerías", Nexo Revista Científica, pp. 104-119, 2018.
[18] J. Memon, S. Memon, M. Bhanger, M. Khuhawar, "Banana Peel: A Green and Economical Sorbent for Cr(III) Removal", Pak. J. Anal. Environ. Chem., pp. 20-25, 2009.
[19] M. Rege, J. Petersen, D. Johnstone, C. Turik, D. Yonge, W. Apel, "Bacterial reduction of hexavalent chromium by Enterobacter cloacae strain HO1 grown on sucrose", Biotechnology Letters, vol. 19, no. 7, pp. 691-694, 1997.
[20] F. Rosales-Ayala, D. Rovira-Quezada, R. Campos-Rodríguez, "Calidad de las aguas residuales de tipo especial en la ciudad La Libertad, El Salvador", Tecnología en Marcha, vol. 32, no. 3, pp. 135-145, Jul.-Sep., 2019. doi: https://doi.org/10.18845/tm.v32i3.4504
[21] L. Torres, J. Cárdenas, M. Moctezuma, V. Martínez, I. Acosta, "Remoción de cromo hexavante por la cáscara de plántano (Musa cavendishii)", Química Hoy, Chemestry Sciences, pp. 29-32, 2012.
[22] SEMARNAT, NOM-001-SEMARNAT-1996, 1996.

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