纤维固载相转移催化剂设计及其催化CO2转化性能研究
Journal: Modern Education Forum DOI: 10.12238/mef.v8i10.13940
Abstract
本文主要论述以市售腈纶纤维为载体,制备新型纤维基相转移催化剂PANNP/QA&PSF-Ag；运用傅里叶红外变换光谱(FTIR)、及元素分析(EA)等技术,验证PANNP/QA&PSF-Ag的微观结构；PANNP/QA&PSF-Ag可在1atmCO2、80℃条件下催化环氧氯丙烷与二氧化碳(CO2)的环加成反应,反应36h后目标产物收率可达41%。此外,提出合理的非均相催化机制。该实验简单可行,适用于化学、药学本科生的创新实验。
Keywords
腈纶纤维；绿色化学；CO2环加成反应；相转移催化剂
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