纤维基相转移催化剂催化CO2转化性能研究
Journal: Journal of International Education Forum DOI: 10.12238/jief.v6i3.7879
Abstract
本文主要论述以市售腈纶纤维为载体,制备新型纤维基相转移催化剂(PANEA-CC-DMPA-BBF)；运用X射线光电子能谱(XPS)、电感耦合等离子体原子发射光谱(ICP-AES)及元素分析(EA)等技术,验证PANEA-CC-DMPA-BBF的微观结构；PANEA-CC-DMPA-BBF可在常压CO2、80oC条件下催化环氧氯丙烷与二氧化碳(CO2)的环加成反应,反应24h后目标产物收率可达46%。此外,提出合理的非均相催化机制。该实验简单可行,适用于化学、药学本科生的创新实验。
Keywords
腈纶纤维；绿色化学；CO2环加成；相转移催化
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